Effect of Chitosan-TiO2 Membrane Performance for the Degradation of Batik Waste with a Photocatalytic Hybrid System

Retno Dwi Nyamiati, Daniel Timotius, Septi Sri Sri Rahmawati, Calista Carissavila, Noor Amalia

Abstract


The treatment of industrial wastewater has gained significant attention in recent years due to its detrimental impact on the environment and public health. This study aims to explore the effectiveness of a photocatalytic hybrid system using a Chitosan-TiO2 membrane for the degradation of batik waste. The performance of the membrane was investigated through a series of experiments, evaluating its ability to remove organic pollutants and enhance the overall treatment efficiency. The morphology, as seen through SEM images, shows a rough surface that enhances photocatalytic efficiency by providing a larger surface area for reactions. The uniform distribution of TiO2 particles within the chitosan matrix is crucial for stable and efficient pollutant degradation during photocatalysis. Furthermore, Chitosan-TiO2 membranes offer a promising solution for batik wastewater treatment. They combine the benefits of chitosan's permeability and organic substance capture with TiO2's photocatalytic capabilities. This integration allows for efficient, one-step hybrid photocatalytic filtration, reducing the use of harmful chemicals and producing environmentally friendlier byproducts. Finally, AAS analysis demonstrated that the addition of TiO2 improved heavy metal degradation in batik waste, with optimal performance observed up to a 89.78% rejection rate, beyond which TiO2 agglomeration occurred.

Keywords


Membrane;Photocatalytic;Chitosan;TiO2; Batik Waste

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References


Dwi Nyamiati, R., Nurkhamidah, S., Rahmawati, Y., & Meka, W. (2023). Kinetic and Thermodynamic Studies in Cellulose Acetate-Polybutylene Succinate ( CA- PBS )/ Single Solvent / Water. Eksergi Universitas Pembangunan Nasional “Veteran” Yogyakarta, 20(1), 9–15.

El-Hefian, E. A., Nasef, M. M., & Yahaya, A. H. (2010). The preparation and characterization of Chitosan / Poly (Vinyl Alcohol) blended films. E-Journal of Chemistry, 7(4), 1212–1219. https://doi.org/10.1155/2010/626235

Fu, J., Wang, X., Ma, Z., Wenming, H., & Li, J. (2019). Photocatalytic ultrafiltration membranes based on visible light responsive photocatalyst : a review. 168, 42–55. https://doi.org/10.5004/dwt.2019.24403

Hashemi, S. A., & Lai, C. W. (2023). An Overview of Photocatalytic Membrane Degradation Development.

Kumar, R., Isloor, A. M., Ismail, A. F., Rashid, S. A., & Ahmed, A. Al. (2013). Permeation, Antifouling and desalination performance of TiO2nanotube incorporated PSf/CS blend membranes. Desalination, 316, 76–84. https://doi.org/10.1016/j.desal.2013.01.032

Maytorena-verdugo, C. I., & Romero-toledo, R. (2020). Chitosan-TiO 2 : A Versatile Hybrid Composite.

Mousa, S. A., Abdallah, H., & Khairy, S. A. (2023). Low ‑ cost photocatalytic membrane modified with green heterojunction TiO 2 / ZnO nanoparticles prepared from waste. Scientific Reports, 1–19. https://doi.org/10.1038/s41598-023-49516-0

Mozia, S. (2010). Photocatalytic membrane reactors (PMRs) in water and wastewater treatment. A review. Separation and Purification Technology, 73(2), 71–91. https://doi.org/10.1016/j.seppur.2010.03.021

Mukimin, A., Zen, N., Purwanto, A., Wicaksono, K. A., Vistanty, H., & Alfauzi, A. S. (2017). Application of a full-scale electrocatalytic reactor as real batik printing wastewater treatment by indirect oxidation process. Journal of Environmental Chemical Engineering, 5(5), 5222–5232. https://doi.org/10.1016/j.jece.2017.09.053

Nasrollahi, N., Ghalamchi, L., Vatanpour, V., & Khataee, A. (2021). Journal of Industrial and Engineering Chemistry Photocatalytic-membrane technology : a critical review for membrane fouling mitigation. Journal of Industrial and Engineering Chemistry, 93, 101–116. https://doi.org/10.1016/j.jiec.2020.09.031

Nurkhamidah, S., Ramadhani, A., Cintya, B., Arief, B., & Nyamiati, R. D. (2019). Indonesian Polymer Journal Article Modified of Cellulose Acetate / Polyethylene Glycol Membrane by the Addition of Graphene Oxide. 22(2), 16–20. https://doi.org/10.37889/mpi.2019.22.2.4

Rahman, M. M., & Rimu, S. H. (2020). Recent development in cellulose nanocrystal-based hydrogel for decolouration of methylene blue from aqueous solution: a review. International Journal of Environmental Analytical Chemistry, 00(00), 1–18. https://doi.org/10.1080/03067319.2020.1817424

Rashidi, H. R., Sulaiman, N. M. N., & Hashim, N. A. (2012). Batik Industry Synthetic Wastewater Treatment Using Nanofiltration Membrane. Procedia Engineering, 44, 2010–2012. https://doi.org/10.1016/j.proeng.2012.09.025

Syamani, F. A. (2020). Cellulose-based membrane for adsorption of dye in batik industry wastewater. 4(6), 281–283. https://doi.org/10.15406/ijh.2020.04.00255

Tung, T. V., Ananpattarachai, J., & Kajitvichyanukul, P. (2018). Photocatalytic membrane reactors for water and wastewater treatment applications: Process factors and operating conditions review. Lowland Technology International, 20(3), 413–424.

Wang, L. (2018). Configurations and Membranes of Photocatalytic Membrane Reactors for Water and Wastewater Treatment Configurations and Membranes of Photocatalytic Membrane Reactors for Water and Wastewater Treatment. IOP Conference Series: Earth and Environmental Science, 208(012078). https://doi.org/10.1088/1755-1315/208/1/012078

Wang, L., Xiong, W., Yao, L., & Wang, Z. (2016). Novel Photocatalytic Membrane Reactor with TiO2 Nanotubes for Azo Dye Wastewater Treatment. 06020, 0–5.




DOI: https://doi.org/10.31315/e.v21i1.10734

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