Adsorbent Size's Impact On Removing Heavy Metals

Mycelia Paradise, Yudha Agung Pratama

Abstract


Numerous variables affect how well adsorption works. The material's surface area is a crucial factor in adsorption. The speed of adsorption by powder material is greater than by granular material. It is related to its surface area. The study aimed to compare the changes of dissolved heavy metals and water pH after adsorption using 60 and 100-mesh adsorbent. A hot plate stirrer was used to carry out adsorption for 5, 10, and 15 minutes. The result showed that the pH of the water changed to neutral after adsorption using 100 mesh adsorbent. Water pH did not meet quality standards after adsorption with 60 mesh adsorbent. The heavy metal Fe in water decreased with an effectiveness rate of 99.5% within 5 minutes of contact time. The concentration of Fe met the quality standards, both in adsorption using 60 and 100 mesh adsorbents. The concentration of Mn did not meet the quality standards. The effectiveness rate of reducing Mn was only 48.6% within 15 minutes of contact time.

Keywords


Adsorption; adsorbent; Fe; Mn; pH

Full Text:

PDF

References


Diharyo, S., Damanik, Z., & Gumiri, S. (2020). Pengaruh Lama Aktifasi Dengan H3po4 Dan Ukuran Butir Arang Cangkang Kelapa Sawit Terhadap Ukuran Pori Dan Luas Permukaan Butir Arang Aktif. PROSIDING SEMINAR NASIONAL LINGKUNGAN LAHAN BASAH, 5(1), 48–54.

Fong, K. F. (2018). Impact of adsorbent characteristics on performance of solid desiccant wheel. Energy, 144, 1003–1012. https://doi.org/10.1016/j.energy.2017.12.113

Franchina, F. A. (2021). Impact of the adsorbent material on volatile metabolites during in vitro and in vivo bio-sampling.

Talanta, 222. https://doi.org/10.1016/j.talanta.2020.121569 Gonzalez, M. N. G. (2022). Life cycle assessment of a nanomaterial-based adsorbent developed on lab scale for cadmium removal: Comparison of the impacts of production, use and recycling. Cleaner Environmental Systems, 4. https://doi.org/10.1016/j.cesys.2022.100071

Indah, S., Helard, D., & Yedriana, R. (2016). Pengaruh variasi konsentrasi logam mangan (Mn) terhadap efisiensi penyisihan logam besi (Fe) pada adsorpsi menggunakan serbuk kulit jagung sebagai adsorben. Jurnal Dampak, 13(2), 100–106.

Keputusan Menteri Lingkungan Hidup Nomor 113 Tahun 2003 Tentang Baku Mutu Air Limbah Bagi Usaha Dan Atau Kegiatan Pertambangan Batubara. (2003).

Khalil, I. (2020). Selective elimination of phenol from hydrocarbons by zeolites and silica-based adsorbents—Impact of the textural and acidic properties. Journal of Hazardous Materials, 384. https://doi.org/10.1016/j.jhazmat.2019.121397

Köse, K. (2020). Applications and impact of nanocellulose based adsorbents. Cellulose, 27(6), 2967– 2990. https://doi.org/10.1007/s10570-020-03011-1

Kumar, P. S., Korving, L., Keesman, K. J., van Loosdrecht, M. C., & Witkamp, G. J. (2019). Effect of pore size distribution and particle size of porous metal oxides on phosphate adsorption capacity and kinetics. Chemical Engineering Journal, 358, 160–169.

Kusumastuti, R. (2014). Analisis Pengaruh Ukuran Butir Karbon Aktif Terhadap Adsorpsi Gas N2 Dan O2 Pada Kondisi Kriogenik. Sigma Epsilon-Buletin Ilmiah Teknologi Keselamatan Reaktor Nuklir, 17(2).

Liu, S. (2019). Modified Silica Adsorbents for Toluene Adsorption under Dry and Humid Conditions: Impacts of Pore Size and Surface Chemistry. Langmuir, 35(27), 8927–8934. https://doi.org/10.1021/acs.langmuir.9b01031

Lv, D. (2018). Selective Adsorption of Ethane over Ethylene in PCN-245: Impacts of Interpenetrated Adsorbent. ACS Applied Materials and Interfaces, 10(9), 8366–8373. https://doi.org/10.1021/acsami.7b19414

Musso, T. B., Parolo, M. E., Pettinari, G., & Francisca, F. M. (2014). Cu (II) and Zn (II) adsorption capacity of three different clay liner materials. Journal of Environmental Management, 146, 50– 58.

Pambayun, G. S., Yulianto, R. Y., Rachimoellah, M., & Putri, E. M. (2013). Pembuatan karbon aktif dari arang tempurung kelapa dengan aktivator ZnCl2 dan Na2CO3 sebagai adsorben untuk mengurangi kadar fenol dalam air limbah. Jurnal Teknik ITS, 2(1), F116–F120.

Paradise, M., Nursanto, E., Nurkhamim, N., & Haq, S. R. (2022). Use Of Claystone , Zeolite, And Activated Carbon To Remove Heavy Metals From Acid Mine Drainage In Coal Mining. ASEAN Engineering Journal, 12(2), 75–81.

Petrovic, B. (2022). Impact of Surface Functional Groups and Their Introduction Methods on the Mechanisms of CO2 Adsorption on Porous Carbonaceous Adsorbents. Carbon Capture Science and Technology, 3. https://doi.org/10.1016/j.ccst.2022.100045

Rahmayani, F., & Siswarni, M. Z. (2013). Pemanfaatan limbah batang jagung sebagai adsorben alternatif pada pengurangan kadar klorin dalam air olahan (treated water). Jurnal Teknik Kimia USU, 2(2), 1–5.

Suliestyah, S., Tuheteru, E. J., & Hartami, P. N. (2018). Pengaruh ukuran butir batubara dan komposisi batubara-ZnCl2 pada daya serap karbon aktif terhadap logam Fe, Cu dan Zn dalam limbah cair. Jurnal Teknologi Mineral Dan Batubara, 14(3), 201–212.

Syauqiah, I., Amalia, M., & Kartini, H. A. (2011). Analisis variasi waktu dan kecepatan pengaduk pada proses adsorpsi limbah logam berat dengan arang aktif. Info-Teknik, 12(1), 11–20.

Yean, S., Cong, L., Yavuz, C. T., Mayo, J. T., Yu, W. W., Kan, A. T., & Tomson, M. B. (2005). Effect of magnetite particle size on adsorption and desorption of arsenite and arsenate. Journal of Materials Research, 20(12), 3255–3264.




DOI: https://doi.org/10.31315/jilk.v5i2.9167

DOI (PDF): https://doi.org/10.31315/jilk.v5i2.9167.g5875

Refbacks

  • There are currently no refbacks.


Copyright (c) 2023 Jurnal Ilmiah Lingkungan Kebumian

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

Editorial Office;

Program Studi Teknik Lingkungan, Fakultas Teknologi Mineral, UPN “Veteran” Yogyakarta.
Jl. SWK 104 (Lingkar Utara) Condongcatur, Sleman, Yogyakarta 55283
Telp./ Fax. (0274) 486400, Email:jurnaltl@upnyk.ac.id

Creative Commons License
Jurnal Ilmiah Lingkungan Kebumian is licensed under a Creative Commons Attribution 4.0 International License.